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Beilstein J. Org. Chem. 2010, 6, 1149–1158, doi:10.3762/bjoc.6.131
Graphical Abstract
Figure 1: Olefin isomerization during ADMET polymerization.
Figure 2: Ru–indenylidene metathesis catalysts C1 and C2, “boomerang” complexes C3, and Hoveyda–Grubbs 2nd ge...
Figure 3: Representative scheme for the in situ generated Ru–indenylidene [38].
Figure 4: Synthesis of the studied α,ω-diene, its ADMET polymerization, and the strategy to evaluate isomeriz...
Figure 5: GPC traces of the polymerizations performed at 60, 80, 100 and 120 ºC in presence of a) 0.5 mol % C1...
Figure 6: GC-MS study of the acid-catalyzed degradation products of polymers P19, P20, P21, and P22.
Figure 7: GPC traces of polymerizations performed with C1 at 80, 100, and 120 ºC. Samples taken at 5 min (―–)...
Figure 8: DSC traces of ADMET polymers P11 and P12 (Table 1, entries 11 and 12, respectively).